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Beilstein J. Org. Chem. 2010, 6, 1070–1078, doi:10.3762/bjoc.6.122
Graphical Abstract
Scheme 1: Structure of the quarterthiophene derivative T1.
Scheme 2: Synthetic route to T1. Reagent and conditions: a) Boc anhydride, CH2Cl2, 6 h, 0 °C–rt, 97%; b) NBS,...
Figure 1: AFM height images of a film spin-coated from diluted gel solution of T1 in MCH (2 × 10−3 M) onto HO...
Figure 2: a) UV-vis spectra of T1 in chloroform (dashed line) and n-heptane (solid line); b) UV-vis spectra o...
Scheme 3: Proposed mode of self-assembly of T1.
Figure 3: UV-vis spectra of T1 (concentration 5 x 10−5 M) in cyclohexane (solid line) and 2.4% MeOH in cycloh...
Figure 4: AFM height images (A and B) of a film spin-coated from MCH solution (concentration 5 x 10−4 M) of a...
Figure 5: Variation of dose-normalized conductivity transients (Δσ/D) with time for T1.